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It is a fusible alloy with a melting point of approximately 70 °C (158 °F)
Not that you would like to use that metal though:
"Wood's metal is toxic because it contains lead and cadmium, and therefore contact with the bare skin is thought to be harmful, especially in the molten state. Vapour from cadmium-containing alloys is also known to pose a danger to humans. Cadmium poisoning carries the risk of respiratory, liver, kidney, and bone damage, loss of sense of smell, and cancer. Field's metal is its non-toxic alternative."
http://en.wikipedia.org/wiki/Wood%27s_metal
So maybe it was Field's metal then.
http://en.wikipedia.org/wiki/Field%27s_metal
Otherwise it's maybe the Leidenfrost effect on lead that had just solidified in the spoon. Molten lead reacts (steam)explosively with water I think.
http://en.wikipedia.org/wiki/Leidenfrost_effect
Here's a lab demonstration: http://www.youtube.com/watch?v=ZcyhUAFoLtI
Note the air bubble that immediately forms around the sphere. The same thing happens in your mouth.
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